Mechanistic Model Compound And Copolymerization Studies of the 4-Substituted-12 4-Triazoline-35-Dione Ring System.

Cover Mechanistic Model Compound And Copolymerization Studies of the 4-Substituted-12 4-Triazoline-35-Dione Ring System.
Mechanistic Model Compound And Copolymerization Studies of the 4-Substituted-12 4-Triazoline-35-Dione Ring System.
Wagener, Kenneth Boone, 1946-
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The data for 86 were as follows: white, odorless solid; m.p.
273-275°; infrared absorbances found at (KBr) 3500 (w, b), 3300 (w, sharp), 2990 (w) , 1770 (m), 1720 (s), 1460 (m, b), 1400 (m) , 1360 (w) , 1330 (w), 1280 (w), 1220 (w) , 1140 (w) , 1080 (w) , 1010 (w) , 860 (w) , 760 (w), 740 (w), 730 (w) , 670 (w) , and 660 (w) cm. ; mass spectrum molecular ion at 330 m/e (sample recrystallized from DMS0-H 2 0); ultraviolet absorbance at (CH_CN) 257 nm, e = 16,000; nuclear O TTia.X magnetic resona
...nce data in Table VIII and spectrum shown in Figure IV.
ftripi Calcd. -For C H N : C. 50.91: H, 4.27; N, 25.45.
„. "• a - "14 '14 b 4 Found: C, 50.95; H, 4.31; N, 25.22.
Rea ction of 84 and 3 ,4 ,5-trideuteriostyrene in methylene chloride 3,4,5-Trideuteriostyrene (0.00100 mol. , 0.107 g.) was added to a solution of 84 (0.00200 mol., 0.226 g.) in 10 ml. methylene chloride resulting in loss of the red color of 84_ in approximately 30 seconds.
The solution was allowed to stand at room temperature for 30 minutes during which 0.143 g.


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