On the Rearrangement of the Tautomeric Salts of 1 4 Diphenyl 5 Thionurazole An
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1209 . 0619 51. 2 504 . 1592 . 1676 . 1031 61. 5 In the next series the alkylation consisted of methyl iodide in a 40 per cent alcohol solution the same sodium phosphate and disodium acid phosphate mixture being used in these ex- periments as in the foregoing series.
Per cent Na Urazole Urazole. Total Ester. O-Esters. Rearranged.
(. 0862) (. 0910) (. 0666) (26) . 1156 . 1194 . 1126 . 1251 . 1134 . 1249 . 1324 . . 1392 . 1094 . 1150 Time Hours.
(6) 12 72 96 168 240 N- and O-Esters.
(. 0666) . 09...57 . 0786 . 0620 . 0556 . 0367 20 41 51 60 If this reaction is monomolecular we would have : ?^~ K, ( C C. , ) K. 2 ( d-f G 2 ), in which C is the original concentration of the sodium \, A- diphenyl-5-thionurazole, Ci that of the l, 4-diphenyl-5-thiol- urazole present at first, and G that of the rearranged salt. When equilibrium is reached K, CC Tf If we substitute -^ K in the first equation and integrate we get K +K = 1 log t c c, c. , K, +K, K. , K, 100 0. 00 10. 00 . 0038 . 0024 . 0014 100 0.
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To quickly assess the difficulty of the text, read a short excerpt:
1209 . 0619 51. 2 504 . 1592 . 1676 . 1031 61. 5 In the next series the alkylation consisted of methyl iodide in a 40 per cent alcohol solution the same sodium phosphate and disodium acid phosphate mixture being used in these ex- periments as in the foregoing series.
Per cent Na Urazole Urazole. Total Ester. O-Esters. Rearranged.
(. 0862) (. 0910) (. 0666) (26) . 1156 . 1194 . 1126 . 1251 . 1134 . 1249 . 1324 . . 1392 . 1094 . 1150 Time Hours.
(6) 12 72 96 168 240 N- and O-Esters.
(. 0666) . 09...57 . 0786 . 0620 . 0556 . 0367 20 41 51 60 If this reaction is monomolecular we would have : ?^~ K, ( C C. , ) K. 2 ( d-f G 2 ), in which C is the original concentration of the sodium \, A- diphenyl-5-thionurazole, Ci that of the l, 4-diphenyl-5-thiol- urazole present at first, and G that of the rearranged salt. When equilibrium is reached K, CC Tf If we substitute -^ K in the first equation and integrate we get K +K = 1 log t c c, c. , K, +K, K. , K, 100 0. 00 10. 00 . 0038 . 0024 . 0014 100 0.
What to read after On the Rearrangement of the Tautomeric Salts of 1 4 Diphenyl 5 Thionurazole An?
You can find similar books in the "Read Also" column, or choose other free books by Ernest Pohl Doetsch to read onlineMoreLess
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