Osmotic Pressure a General Discussion

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Osmotic Pressure a General Discussion
Faraday Society
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It was shown (II, 148) that if the molecular depression of the freezing-point were reckoned upon the free water, instead of the total water, a constant value was obtained ; that is to say, it was shown that = F = 1-867, Nz 1, 000 where w is the free water in 1, 000 grams of water and N is the molecular concentration of the solute per 1, 000 grams of water. Since N = y> iSL = ~J? an d F = F - 1 '- 00 ? he i, ooo h e CONSTITUTION OF WATER : MR. W. R. BOUSFIELD 33 TVC can put the expression into t...he form F' ~~ h n which is the relation C = D above given.
This relation has since been found to give accurate results in every case in which it has been tested. A difficulty is that the value of F derived from freezing-point measurements of different observers is found to vary. The value 1*867 was deduced from Jahn's freezing-point determinations in the case given above. Bedford's figures * give values from 1*86 to 1*867. Morse and Frazer's figures f for sugar solutions give the value i'855.
The relation A = D is founded primarily on the measurements of the osmotic pressures of sucrose solutions at 20 C.


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