Papers On Pyrimidines

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Papers On Pyrimidines
Henry Lord Wheeler
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It separated in long needles^ which melted at 2101 to an oil, without effervescence. It con- tained sulphur and gave a violet colored solution by treatment with bromine water and barium hydroxide. Analysis (Kjeldahl): Calculated for C 7 Hi O 2 N 2 S, N 15. 05; found, 15-05- NEW HAVEN, CONN.
[Reprinted from The American Chemical Journa Vol. XLJI. No. I. July, 1909. ] [Contributions from the Sheffield Laboratory of Yale University. ] CLXVIL RESEARCHES ON PYRIMIDINES: THE PREPARATION OF 3-METHYL-
...AND 3- BENZYLURACIL. [FORTY-THIRD PAPER. ] BY HENRY L. WHEELER AND TREAT B. JOHNSON.
From a theoretical standpoint a larger number of alkyl com- pounds may result by alkylating a uracil derivative than can be obtained by a similar treatment of a 2-mercapto-6-oxy- pyrimidine. With the mercaptopyrimidines only three mono- derivatives should result. With uracil, 4-methyluracil, thy- mine, or 5-methyluracil, in each case there are ten possible compounds, four mono- and six dialkyl derivatives. This includes oxygen derivatives, but not tautomeric forms.


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