Per Acids And Their Salts

Cover Per Acids And Their Salts
Per Acids And Their Salts
T Slater Thomas Slater Price
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This objection is not necessarily valid, however, since the local concentration of the hydrogen peroxide produced at the anode may be sufficient for the purpose. The hydrogen peroxide would be produced by the discharge of OH'-ions contained in the solu- tion of sodium orthoborate used. It is true that Riesenfeld and Reinhold, 10 owing to the ready decomposition of hydrogen peroxide in the presence of sodium hydroxide, were unable to obtain it at the anode by the electrolysis of solutions of sod...ium hydroxide, although it was formed in quantity when potassium hydroxide was used. In the electrolysis of the solution of the orthoborate the conditions are probably more favourable for the existence of hydrogen peroxide than in solutions of pure sodium hydroxide. Sodium perborate, NaBO 3, 4H 2 O, forms large, transparent, monoclinic prisms, which are stable in the air. * By careful dehydration the monohydrate, NaBO 3, H 2 O, can be obtained ; the remaining molecule of water can be removed in a vacuum over phosphoric oxide.

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