Photo Chemistry

Cover Photo Chemistry
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As will be indicated later in dealing with the photo-chemical processes in flames and other self-luminous bodies, the actual emission- centres appear to be electro-positively charged particles or kations. By a katastase then we shall understand a shell or equipotential system of such kations. The fact that elements like the halogens may also assume the self-luminous state need Digitized by VjOOQIC DYNAMICS OF PHOTO-CHEMICAL CHANGE 251 not militate against this terminology, as there is a conside...rable amount of evidence showing that conventionally "negative" elements such as chlorine can pass into a relatively positive condition, just as "positive" elements such as copper may form part of an electro-negative group or complex anion, under appropriate conditions.
§ 94. Endo- and Exo-actinic Reactions.
Just as in thermo-chemistry we are familiar with reactions which are exo-thermic and endo-thermic, according as they are concomitant with the evolution or the absorption of heat, so we have exo-actinic and endo-actinic reactions in photo- chemistry, corresponding to the emission and absorption of light.


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