Physical Chemistry Its Bearing On Biology And Medicine
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It is possible however for a compound con- taining the S0 4 group, such as potassium ethyl sulphate, to dissolve without being ionised, or to ionise in a different way from ordinary sulphates, and in such a case the addition of barium chloride may not cause any precipitation whatsoever. Similarly, the failure of silver nitrate to precipitate phenyl bromide in alcoholic solution is to be attributed to the non-iohisation of phenyl bromide. From the point of view, then, of the electrolytic dissoci...ation theory, the reactions which are so largely employed in analytical chemistry are ionic reactions, and the behaviour of a salt in dilute solution may be regarded as the reactions of the positive ion plus those of the negative ion. The observation that a compound which is very reactive in dilute aqueous solution frequently loses this character when dissolved in a non-ionising solvent is instructive in this connection. Thus acids in aqueous solution are characterised by their power of acting on carbonates, and yet a solution of dry hydrogen chloride in benzene a solution, it should be observed, which does not conduct the electric current is unable to attack dry sodium carbonate.
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To quickly assess the difficulty of the text, read a short excerpt:
It is possible however for a compound con- taining the S0 4 group, such as potassium ethyl sulphate, to dissolve without being ionised, or to ionise in a different way from ordinary sulphates, and in such a case the addition of barium chloride may not cause any precipitation whatsoever. Similarly, the failure of silver nitrate to precipitate phenyl bromide in alcoholic solution is to be attributed to the non-iohisation of phenyl bromide. From the point of view, then, of the electrolytic dissoci...ation theory, the reactions which are so largely employed in analytical chemistry are ionic reactions, and the behaviour of a salt in dilute solution may be regarded as the reactions of the positive ion plus those of the negative ion. The observation that a compound which is very reactive in dilute aqueous solution frequently loses this character when dissolved in a non-ionising solvent is instructive in this connection. Thus acids in aqueous solution are characterised by their power of acting on carbonates, and yet a solution of dry hydrogen chloride in benzene a solution, it should be observed, which does not conduct the electric current is unable to attack dry sodium carbonate.
What to read after Physical Chemistry Its Bearing On Biology And Medicine?
You can find similar books in the "Read Also" column, or choose other free books by James Charles Philip to read onlineMoreLess
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