Physics And Inorganic Chemistry a Manual for Students And Practitioners

Cover Physics And Inorganic Chemistry a Manual for Students And Practitioners
Physics And Inorganic Chemistry a Manual for Students And Practitioners
Alexius Mcglannan
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, 142; G. F. , O-=P.
NOH 3. Trisodium phosphate or tertiary sodium phosphate ; /ONa M. F. , Na 3 P0 4 ; M. W. , 164; G. F. , O=P^- ONa.
X)Na All alkali phosphates, but only the primary phosphates of other metals, are soluble in water.
PREPARATION. 1. Natural phosphates are salts of orthophosphoric acid, whence it may be obtained by sulphuric acid (see page 119).
2. By dissolving phosphoric oxide in water and boiling.
3. By treating phosphorus with dilute nitric acid, and evaporating the solutio
...n until any excess of nitric acid has been expelled.
VARIETIES. Orthophosphoric add, (phosphoric acid, U. S. P. ), Sp. G. 1. 710, contains 85 per cent, of pure acid.
Dilute phosphoric acid, U. S. P. , contains 10 per cent, of pure acid.
Qualitative Analysis of Phosphoric Acid and the Phosphates.
1. A neutral solution of a phosphate precipitates solutions of barium, calcium, or ferric chloride, forming the respective phosphates, which are soluble in acid.
2. Silver nitrate forms with phosphates a yellow precipitate soluble in ammonia and in nitric acid.


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