Problems in Physical Chemistry With Practical Applications

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Problems in Physical Chemistry With Practical Applications
Edmund Bridges Rudhall Prideaux
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In another experiment at the same temperature, and p 720 mm. , 73 per cent, of an original volume of HCl (34*1 c. C. ) was transformed at equilibrium. If K p = 2*0, find the initial volume of oxygen.
Answer 15*9 c. C.
Haber (" Thermodynamics of Technical Gas Reactions, " p. 181).
16. A mixture of 80$, 0% and jV 2 in the molecular pro- portions 2*62 : 1 : 3*76 was passed through a silica tube at 1, 001 absolute (Bodenstein und Pohl, Zeitsch. Elektro- chem. (1905), 2, 273). The resulting equilibr
...ium mixture rapidly cooled was found to contain : SO* : S0 3 : 2 = 33*9 : 17'5 : 10'9 mols. P = 759 mm. Throughout.
Find the equilibrium constant K c, and an expression for the percentage yield ^^ - which would be obtained if JV 2 were absent from the mixture of 2 and 2 in the above ratio. The combination is effected at 760 mm.
Note The amount of nitrogen associated with the resul- tant mixture must be found and included in the total number of molecules (N) (see equation (6) p. 141).
*X x N Q, x / ~N~~ ' To find the amount x of O 2 transformed, if there is no PKOBLEMS IN PHYSICAL CHEMISTEY 153 N z, equate the product 2*62 - 2 x etc.


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