Solutions

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1 I have calculated these diminutions, approxi- mately, for the vapour-pressures at 100. Solutions con- taining one molecular weight, in grams, of the following salts, in 1, 000 grams of water, showed the diminutions of vapour-pressures which are noted : NaCl = 27, Na 2 S0 4 = 26, NaN0 3 = 25, KC1 = 24, K 2 S0 4 = 32, KN0 3 = 22, KOH. 2H 2 = 19, NaOH. 2H 2 = 22, CaCl 2 . 6H 2 = 35. These numbers show a rough approximation. Some of the values for instance, the small number for potash may perhaps... be ascribed to inaccuracies in the estimations of the percentage contents of the solutions. I append a few examples, taken from the very large collection of experimental data, in order to illustrate the relations which have been sketched. SODIUM CHLOKIDE Temp. P 5 p. Ct. 10 p. Ct. 20 p. Ct. 30 p. Ct. Mean. 1 p. Ct. V ~ 19-9 17-38 0-98 1-47 4-06 149 0086 35-0 41-82 1-79 3-11 8-13 30 0072 49-8 91-09 2-84 5-81 11-36 18-20 62 0068 64-8 185-27 9-88 21-45 1-09 0059 82-2 388-33 21-58 46-20 2-24 0058 100-5 775-40 44-90 92-41 4-45 0057 1 This inference was drawn by me in 1883, when I was preparing the first edition of my Lehrbuch, part i.

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