Stoichiometry

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Soc. Edin. (1851). * p ogg. Ann. , 103, 206 (1858). *Ckem. News, 42, 130 and 313 (1880) ; 43, 19 (1881).
5 Nature, 24, 239 (1881); cf. Pettersson, ibid. , p. 167.
15 226 5 TOICHIOME TR V In 1883 and 1884 Ramsay and Young 1 proved experimentally (a) that the volatilizing points of ice and other vaporizible solids depend on the pressure; (b) that the same curve represents the volatilizing points and the vapour pressures of a given solid ; and (c) that the curve for ice agrees with that based on t
...he formulae em- ployed by James Thomson. Experimental confirmation of the correctness of James Thomson's conclusions was obtained by Fischer 2 in 1886 in the case of ice, and by Ferche 3 in 1891 in that of benzene by the statical method.
J. H The value of - for a volatilizing solid was calculated by James Thomson in the following manner : The heat of volatilization of a solid is given by the equation, L" = (v v - v s )- x ^L a i where v v and v s are the volumes of a gram of vapour and solid re- spectively, and -~^ is the rate of increase of the vapour pressure of the solid per unit rise in temperature.


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