Studies From the Rockefeller Institute for Medical Research, volume 23
Studies From the Rockefeller Institute for Medical Research, volume 23
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iv. monohalogenacylated slmple amines, ureas, and Urethanes, and the Hexamethylenetetraminium Salts Derived Therefrom.
By WALTER A. JACOBS and MICHAEL HEIDELBERGER.
(From the Laboratories of The Rockefeller Institute for Medical Research.) (Received for publication, March 30, 191 5.) With but one exception, the hexamethylenetetraminium salts described in this paper are purely of aliphatic origin and were ob- tained from the halogenacyl compounds and hexamethylenetetra- mine by the methods descr...ibed in the previous papers. The salts are all easily soluble in water. On standing, more rapidly on warm- ing, the solutions decompose with the liberation of formaldehyde and other products, which, contrary to the behavior observed with the aromatic compounds, remain in solution. A search of the literature has revealed to us the description of the chloroacetyl derivative of but one simple aliphatic amine; viz., chloroacetylallylamine. 1 Our work has necessitated the preparation of the chloroacetyl com- pounds of several of the simpler amines and the preparation and properties of these will be found below.
What to read after Studies From the Rockefeller Institute for Medical Research, volume 23?
You can find similar books in the "Read Also" column, or choose other free books by Rockefeller Institute for Medical Research, Rockefeller Institute to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
iv. monohalogenacylated slmple amines, ureas, and Urethanes, and the Hexamethylenetetraminium Salts Derived Therefrom.
By WALTER A. JACOBS and MICHAEL HEIDELBERGER.
(From the Laboratories of The Rockefeller Institute for Medical Research.) (Received for publication, March 30, 191 5.) With but one exception, the hexamethylenetetraminium salts described in this paper are purely of aliphatic origin and were ob- tained from the halogenacyl compounds and hexamethylenetetra- mine by the methods descr...ibed in the previous papers. The salts are all easily soluble in water. On standing, more rapidly on warm- ing, the solutions decompose with the liberation of formaldehyde and other products, which, contrary to the behavior observed with the aromatic compounds, remain in solution. A search of the literature has revealed to us the description of the chloroacetyl derivative of but one simple aliphatic amine; viz., chloroacetylallylamine. 1 Our work has necessitated the preparation of the chloroacetyl com- pounds of several of the simpler amines and the preparation and properties of these will be found below.
What to read after Studies From the Rockefeller Institute for Medical Research, volume 23?
You can find similar books in the "Read Also" column, or choose other free books by Rockefeller Institute for Medical Research, Rockefeller Institute to read onlineMoreLess
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