The Arrangement of Atoms in Space

Cover The Arrangement of Atoms in Space
The Arrangement of Atoms in Space
J H Van T Jacobus Henricus Hoff
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). Arabite (act. ).
Inact. Trioxygl. Act. Trioxygl.
H 2 COH H 2 COH HCOH HCOH HCOH HCOH HCOH HOCH OCH OCH Lyxose. Xylose.
Lyxonic acid. Xylonic acid.
Xylite (inact. ). Act. Trioxygl. Inact. Isomeric trioxygl.
H 2 COH H 2 COH HCOH HCOH HOCOH HOCH HOCOH HCOH OCH OCH Glucose group. It has already been mentioned that glucose and mannose have the formulae I B a, @. The choice is rendered possible by the fact that the same saccharic acid which results from the oxidation of glucose is obtained also fr
...om an 88 STEREOCHEMISTRY OF CARBON isomeric gulose ; l only the formula I B a admits of such an isomer, and therefore the configuration of mannose and gulose, of mannosaccharic and sac- charic acid, is at once settled, as well as that of the corresponding mannite and sorbite, which are formed on reducing mannose 2 and glucose 3 respectively.
Glucose. Mannose. Gulose.
Saccharic acid. Manno-saccharic acid. Saccharic acid. Sorbite. Mannite. Sorbite.
H 2 COH H 2 COH H 2 COH HCOH HCOH HCOH HCOH HCOH HOCH HOCH HOCH HCOH HCOH HOCH HCOH OCH OCH OCH At the same time this determines the configura- tion of levulose.


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