The Catalytic Preparation of Mercaptans

Cover The Catalytic Preparation of Mercaptans
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6 53. 8 2. 0 23. 2 Remaining by dif.
%.
73. 9 61 . '3 51. 7 53. 0 47. 6 39. 9 31. 0 27. 8 29. 2 21. 0 Sabatier, "La Catalyse, " 2nd Ed. , Paris, 1920, p. 261.
11 60% 50% best rate. Doubling the time results in a very slight increase in the amount of mercaptan with a considerable increase in the by-products.
Ratio of Reactants.
A brief study was made of the ratio of the reactants. The hydrogen sulfide which passes out of the reaction tube mixed with hydrogen and hydrocarbon is a loss and the gre
...ater its volume the more of the mercaptan it carries along with it. On the other hand, the amount of alcohol lost in side reactions is greater when it is in excess. A series of deter- minations was made at 380 passing 74 g. Of n-butyl alcohol over the catalyst mixed with varying amounts of hydrogen sulfide. The results are given The 1 : 1 ratio gives the best results.
401 2CI O. I Lo

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