The Chemistry of the Non Benzenoid Hydrocarbons And Their Simple Derivatives
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), d 2QO 0. 9204, H D 1. 4929. No crystalline hydrochlorides or hydrobromides of cedrene are known.
Tricyclic non-benzenoid hydrocarbons have been made by the catalytic hydrogenation of tricyclic benzenoid hydrocarbons such as anthracene and phenanthrene. By the hydrogenation of phenan- threne at the remarkably high temperatures of 360, under high pres- sure, Ipatiev 66 obtained the completely reduced hydrocarbon C 14 H 24, which he calls perhydroanthracene. It is an oil distilling at 270- 276 ...and does not crystallize at 15. It is inert to permanganate solu- tion and bromine in the cold, and also practically unacted upon by sulfuric-nitric acid nitrating mixture.
Anthracene was reduced by Godchot 67 over nickel at 260 to tetrahydroanthracene, the constitution of which is unknown. It crys- tallizes from alcohol in plates melting at 89 and distilling at 309. At a little higher temperature, 200-205 octohydroanthracene, melt- ing-point 71 and distilling at 292-295, is formed, and at 260-270 and under about 125 atmospheres pressure Ipatiev 68 succeeded in reducing it to decahydroanthracene, melting-point 73-74, and finally to the completely reduced hydrocarbon, perhydroanthracene, an oily liquid.
What to read after The Chemistry of the Non Benzenoid Hydrocarbons And Their Simple Derivatives?
You can find similar books in the "Read Also" column, or choose other free books by Benjamin T Benjamin Talbott Brooks to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
), d 2QO 0. 9204, H D 1. 4929. No crystalline hydrochlorides or hydrobromides of cedrene are known.
Tricyclic non-benzenoid hydrocarbons have been made by the catalytic hydrogenation of tricyclic benzenoid hydrocarbons such as anthracene and phenanthrene. By the hydrogenation of phenan- threne at the remarkably high temperatures of 360, under high pres- sure, Ipatiev 66 obtained the completely reduced hydrocarbon C 14 H 24, which he calls perhydroanthracene. It is an oil distilling at 270- 276 ...and does not crystallize at 15. It is inert to permanganate solu- tion and bromine in the cold, and also practically unacted upon by sulfuric-nitric acid nitrating mixture.
Anthracene was reduced by Godchot 67 over nickel at 260 to tetrahydroanthracene, the constitution of which is unknown. It crys- tallizes from alcohol in plates melting at 89 and distilling at 309. At a little higher temperature, 200-205 octohydroanthracene, melt- ing-point 71 and distilling at 292-295, is formed, and at 260-270 and under about 125 atmospheres pressure Ipatiev 68 succeeded in reducing it to decahydroanthracene, melting-point 73-74, and finally to the completely reduced hydrocarbon, perhydroanthracene, an oily liquid.
What to read after The Chemistry of the Non Benzenoid Hydrocarbons And Their Simple Derivatives?
You can find similar books in the "Read Also" column, or choose other free books by Benjamin T Benjamin Talbott Brooks to read onlineMoreLess
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