The Compendious Manual of Qualitative Chemical Analysis

Cover The Compendious Manual of Qualitative Chemical Analysis
The Compendious Manual of Qualitative Chemical Analysis
Eliot Charles William
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[ 66. Of the tube. The test is best applied to a nitric acid solu- tion of the substance ; shaking vigorously after addition to the molybdate of ammonium solution, and if necessary, warming gently (not above 70 C. ). If the precipitate does not appear in a few minutes, a few drops more of the solu- tion to be tested may be added. Let the mixture stand for at least half an hour to detect traces of phosphoric acid. This precipitate is soluble in an excess of phosphoric and other acids; and certai...n organic substances may prevent its formation. A yellow coloration of the liquid merely is not enough to prove beyond question the presence of a phosphate ; a precipitate must be waited for. The yellow precipitate can be easily recognized, even in dark-colored liquids, when it has settled. *<. when="" the="" previous="" steps="" of="" analysis="" have="" proved="" that="" phosphates="" present="" in="" solution="" under="" examination="" are="" soluble="" ammoniacal="" liquids="" and="" no="" arsenic="" acid="" or="" arseniates="" following="" test="" will="" identify="" a="" phosphate="" free="" phosphoric="" :="" .="">

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