The Electrolytic Dissociation Theory

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of two structural isomers. That is> phosphorous acid also exists in two isomers of tautomeric form, and so for this acid it Ukewise appears that high heat of dissociation (great temperature coefficient of the conductivity^ Arrhe- nius) is bound up with the possibility of intermolecular reaction.
NON-AQUEOUS SOLUTIONS.
All our previous discussions concerning dissociation have been confined to solutions in which water was the solvent. This was done not alone for the reason that the investigation
...of dissociation and conductivity was first carried through on aqueous solutions, but because here we have arrived at comparatively simple results, and because the property of behaving as an electrolyte is an especially conspicuous pecuKarity of the particular compounds when dissolved in water. The capacity for ionic decomposition of those substances which have been recognized as electrolytes in water also makes its ap- pearance more or less distinctly in other solvents. In fact, the nature of the solvent plays an exceedingly important rdle, so that it has been possible to arrange the various media in a series according to their " dissociat- ing " power, which series agrees for most solutes.

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