The Electromotive Force And Free Energy of Dilution of Lithium Chloride in Aqueo

Cover The Electromotive Force And Free Energy of Dilution of Lithium Chloride in Aqueo
The Electromotive Force And Free Energy of Dilution of Lithium Chloride in Aqueo
Franklin Spencer Mortimer
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10067 0. 05-0. 005. 9608 Methyl ale. . .
9205 7698 6911 Ethyl ale 8564 6919 5928 w-Propyl ale 7608 5684 CC4. 8 w-Butyl ale. . .
796l 7450 5587 4834 Isoamyl ale. .
6764 6031 5162 4149 1 "Leitvermogen 2 Extrapolated.
der Elektrolyte, " p. 201.
It will be observed that for a given normality ratio (10 : i) the free energy of dilution of lithium chloride decreases regularly as we pass from the lower to the higher members of the same homologous series. Further- more, for any one of the solvents studi
...ed the free energy decreases as the pair of concentrations involved become more dilute. Since the free energy of dilution is proportional to the logarithm of the ratio of the activities of the chlorine ions, we should expect, for the normality ratio used, that the free energy would increase to a maximum at infinite dilution.
Table VI gives a summary of the activity ratios of the ions as calculated by a simple rearrangement of Equation 4. This ratio in the various sol- vents decreases with increase in dilution of the pairs constituting the cells, and this in spite of an increase in the normal ionization of the electrolyte.


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