The Elements of Stereochemistry

Cover The Elements of Stereochemistry
The Elements of Stereochemistry
Arthur Rudolf Hantzsch
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For example, recently, the derivatives of thiophene antialdoxime, 160 ELEMENTS OF STEREOCHEMISTRY C 4 H 3 S C H II HO N have been obtained, although the parent compound is not stable in the free state ; in the same way the existence of antioenanthaldoxime which is still less stable appears to be beyond doubt, from the way in which certain of its derivatives behave. Finally Franchimont 1 has been able to prepare two isomeric acetaldoximes.
Influence of constitution on configuration. The influ- e
...nce 2 of configuration on constitution has been less studied in the case of the oximes than in the case of the ethylene derivatives. The existence and intramolecular reactions of two derivatives, R' C R" R' C R" H and || HO. N N OH depend to such an extent on the two radicals R' and R", and occur in such a regular way, that one is able to systematically classify these radicals according to their affinity for the oximidohydroxyl and to predict before- hand the properties of an oxime of a given constitution, if one knows the nature of the two groups R' and R".

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