The Foundations of Chemical Theory

Cover The Foundations of Chemical Theory
The Foundations of Chemical Theory
R M Robert Martin Caven
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When hydrogen chloride is dissolved in water it is ionized thus: HC1 ^ H- + C1', and sodium hydroxide thus: NaOH ^: Na' + OH'.
Water, however, which is not an electrolyte, is ionized thus: H 2 O == H' + OTT, to the minutest extent; only, indeed, to the extent of 1 grm. -mole- cule in 10 million litres. Since, therefore, H* and OH 7 ions cannot coexist in the same solution, they will combine when solutions which separately contain these ions are mixed. Now a solution which contains H* ions conta
...ins an acid; indeed, according to the theory of ionization, degree of acidity depends essentially upon the concentra- tion of hydrogen ions; whilst a solution containing OH' ions is a solution of a base, that is of an alkali, the strength of which depends similarly on the concentration of OH' ions. When, therefore, solu- tions of an acid and an alkali are brought together, e. G. Solutions of HC1 and NaOH, a reaction such as the following takes place: H' + Cl' + Na- + OH' = HOH + Na- + Cl'.
168 CHEMICAL THEORY The process of neutralization is the reaction: H- + OH' = HOH, and there is no other reaction.


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