The Freezing-Point

Cover The Freezing-Point
The Freezing-Point
Harry Clary Jones
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9 98. 4 o. Oio 99. 5 93. 7 0. 050 90. 4 88. 4 An absolute agreement between the dissociation values obtained by the conductivity method and by the freezing- point method, is not to be expected, since the former method was used at 18 or 25, while the latter was 24 THE FREEZING-POINT METHOD applied at about o ; and further, the hydration of the dissolved substance produces a greater effect upon the results of the freezing-point, than upon the results of the conductivity method, as has been shown ...by Jones and Pearce. 1 1 Amer. Chem. Journ. , 38, 683 (1907).
PART II.
THE BOILING-POINT METHOD THEORETICAL The presence of a foreign, non-volatile substance diminishes the vapor pressure of the solvent in which it is dissolved. Since the boiling-point of a solvent, or of a solution, is the temperature at which the vapor-pres- sure just overcomes the pressure of the atmosphere, it follows that the solution having a lower vapor-pressure than the solvent, will have a higher boiling-point.
There are thus two quantities, either of which we may measure : The depression of the vapor-tension of the sol- vent, caused by the presence of the dissolved substance; or the rise in the boiling-point of the solvent, due to the same cause.


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