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The Fundamental Laws of Electrolytic Conduction Memoirs By Faraday Hittorf And

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Ann. , 46, 29, 1892. ] 68 LAWS OF ELECTROLYTIC CONDUCTION I chose such currents that a sufficient amount of silver was reduced before it began to drop off. When this threatened to occur the electrolysis was stopped.
Solution I Specific gravity at 11. 1 C. : 1. 3079.
It contained 1 part NAg to 2. 48 parts water.
The current reduced 1. 2591 gr. Ag in 1-J hours at a temper- ature of 11. 2 C.
The solution about the cathode gave : Before electrolysis. . . 17. 4624 gr. ClAg After " . 16. 6796 " " It
...lost 0. 7828 gr. ClAg, or 0. 5893 gr. Ag.
Hence the amount of the transferred silver is 1. 2591 -0. 5893 6698 0. 6698 gr. , or " Ut/u =53. 2 per cent.
Solution II Specific gravity at 19. 2 C. : 1. 2788.
It contains 1 part NAg to 2. 735 parts water.
The current from one cell reduced 1. 909 gr. Ag at 19 C.
The solution at the cathode gave : Before electrolysis. . . 15. 9364 gr. ClAg After " . 14. 7233 " " The loss is 1. 2131 gr. ClAg, or 0. 9132 gr. Ag.
The transference of silver is therefore 1. 909 -0.


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