The Manufacture of Chemicals By Electrolysis

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The Manufacture of Chemicals By Electrolysis
Arthur James Hale
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, 1916, 575.
52 THE MANUFACTURE OF CHEMICALS BY ELECTROLYSIS by Byers and Walter, 1 and other valuable contributions to our knowledge of tbis subject bave been recently made, which render important aid in the study of a process of which little is known at the present time, although its industrial importance is considerable.
The term electro-oamosis refers to the passage of a liquid through a membrane during electrolysis. The flow of liquid through this membrane which separates anode from cathod
...e depends upon current strength, the resistance of the liquid, and the thickness and porosity of the membrane.
Cohen 2 has shown that during electro-osmosis both liquid and diaphragm become electrically charged with charges of opposite sign.
According to Bancroft, 3 the charge on the diaphragm, which controls the direction of the osmotic flow, depends upon the relative adsorption of anions and cathions, being positive if cathions are adsorbed to a greater extent than anions. The same view is held by T.


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