The Oxidation of Isopropyl Alcohol Acetone And Butyl Compound By Neutral And a
The Oxidation of Isopropyl Alcohol Acetone And Butyl Compound By Neutral And a
Lily Bell Sefton
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, and 75 C. , respectively, plotted against initial alkali concentra- tions. Fig. 5 shows oxalic acid yields from oxidations at the three tempera- tures given; Fig. 6 the carbonic acid yields and Fig. 7 the acetic acid yields. Logarithmic curves corresponding to those are given in Figs. 8, 9, and 10. Reference has been made to the fact that there is a difference of opinion concerning the action of neutral permanganate solution on acetone. Some- time after St. Gilles 5 made the statement that ac...etone was unaffected by permanganate solution, F. Sachs 6 used boiling acetone as a medium for affecting the oxidation of certain benzyl compounds with permanganate. Martines 7 used a solution of permanganate in acetone for the oxidation of menthones. The most recent published work on acetone 8 confirms the findings of St. Gille, Sachs, and Martines. Witzemann added solid permanganate to a neutral solution of acetone and allowed it to stand for several weeks. At the end of that time there was no indication of action between the two substances.
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