The Physical Chemistry of the Metals

Cover The Physical Chemistry of the Metals
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95 96 97 98 99 100 Volume per cent Bi FlG. 41.
resistance which they encounter in their motion under the influ- ence of the e. M. F. Becoming greater due to the increase of internal friction. Electrons and molecules both diffuse in the solid metal- lic solutions; we have accordingly to do with the diffusion of a mixture. The kinetic theory allows us to draw certain con- clusions concerning the friction in a gas mixture, which have been found to agree with the experimental facts. The vis- co
...sity of a gas is increased by the addition of a second gas even though the second gas possesses a smaller coefficient than the 80 THE PHYSICAL CHEMISTRY OF THE METALS first. (This is true only in certain cases, and is not true in case of oxygen-hydrogen, nitrogen-hydrogen, hydrogen-helium or oxygen-nitrogen, but is true for carbon dioxide-hydrogen and helium-argon). Graham, and later Puluj, both obtained the remarkable, and on first thought improbable, result, that the internal friction of C02 is not lowered but raised by the addition of a small amount of hydrogen.

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