The Polariscope in the Chemical Laboratory; An Introduction to Polarimetry And Related Methods
The Polariscope in the Chemical Laboratory; An Introduction to Polarimetry And Related Methods
George William Rolfe
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Multirotation seems to be a phenomenon resulting from hydration of the substance, accompanied by a rearrange- ment of the optically active groups, but it has not been completely explained. Laws of Hydrolytic Change. — The polariscope has been of great service to science as a means of measurement of comparative chemical activity of hydrolyzing substances, particularly acids ; and, as the constants so obtained have a very direct and intimate relation to those determined by electrical conductivity... and other methods of measurement of chemical aifinity, they are usually termed " affinity con- stants." Wilhelmy, in 1850, was the first to formulate a mathe- matical expression of the laws governing the chemical change produced by hydrolysis. Thereby was opened up a field of research which has had enormous influence on the science of chemistry as a whole, and greatly widened ^ Pentose sugars (CgHioOs). Digitized by LjOOQIC 252 THE POLARISCOPE IN SCIENTIFIC RESEARCH our comprehension of the mechanism of chemical action.
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