The Preparation of Benzoic Acid By Oxidation of Toluol

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This Y/ould have heen the most su.itahle pointfor a pressure gauge, "but it was not found convenient to insert one.
In mailing the runs, a measured arnou.nt of acid was pi ced in the box, and the box wa- then supported on a water bath. The cover was placed on the box and all craclis were stopped v/ith the BaSO^, , asbestos water-glass mixture. The cover was held in place b" suitable clamps. T"^e tem- perature in the box v;as raised to 85 0., and then the toluene wa^^ heated. The toluene vapor t
...hen passed over into the acid mixture. The valve between the box and condenser v/as closed.
15.
Oxidation of Toluol to Benzoic Icid In the first run tlie toluene came through quite vigorously, "but the distrihution v/as not v;hat v/as desired. l.Iost of the vapor escaped through the first fev/ holes. In the second run this was corrected "by sealing these holes v/ith water-glass. In this latter run the distrihu- tion was very satisfactory. Considerable toluene vapor was ohserved ahove the acid surface.


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