The Principles of Inorganic Chemistry;

Cover The Principles of Inorganic Chemistry;
The Principles of Inorganic Chemistry;
Wilhelm Ostwald
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Hydrochloric acid is regenerated and can be used for dissolving further quantities of carbonate.
In order to convert barium sulphate into other barium compounds, it is reduced with charcoal to barium sulphide, which can be readily decomposed by acids with evolution of sulphuretted hydrogen. By fusion with excess of alkali carbonate it is converted into barium carbonate ; the alkali ' sulphate which is formed can be removed by washing.
536. Barium Carbonate, BaC0 3 , occurs naturally, as ivither
...ite, in rhombic crystals which are isomorphous with aragonite and stronti- anite. It is used as a convenient starting material for the manu- facture of other barium salts, for which purpose the substance is decomposed by acids. Its conversion into oxide by heating is not practicable, because the temperature of measurable dissociation is too high.
On bringing the ions Ba" and C0 3 " together, barium carbonate is obtained as a white precipitate, readily soluble in almost all acids.
In preparative chemistry, pure barium carbonate is very largely used for the preparation of the barium salts of the most varied acids.


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