The Synthetic Manufacture of Phenol

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The water then was shut ,cff and the blo«A/ line openea, the vent line closed, 15 pounds of air a,p plied at the surface of the fusion, and the fusion was blown to a separatoi lor acidification. During the whole operation, except when the caustic was first char^^-ed, the agitator was in motion.
Theoretically S'Oda salt and caustic should be fused in the latio of £.£5 to 1. I belitve, hovv'evei , that the most efficient ratio, taking- everything into corsiderat ion, is 1.5 to 1.
C, H^ SO, Ka + £
... i:a OK •> DO 3 4845# 2150# C^ H .OEa + ra^ SO, + H^O 6 5 2 3 £ 3l£2f 338 485# (Ratio of £.£5 to 1 theoretical) 57 Finished, fusions varied considerably, some being so thick that they could not be agitated, while others had the thinness of water, A fev/ gave a crude that was white to straw color, but these were late, the majority giving a crude that was reodish to biovvnish black. This dark color was largely due to chaired soaa salt and decomposition ^jioducts.
Some kettles were hotter than others and soiree kettles had better agitation than others.


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