The Theory And Practice of Electrolytic Methods of Analysis
The Theory And Practice of Electrolytic Methods of Analysis
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It follows therefore that this method stands far behind the two methods first described as regards simplicity and ac- curacy.
The electrolytic method of separating copper and silver could receive a practical application in the analysis of silver coining- metal, and this use of it will receive further notice in Part III. , D.
Copper from Quicksilver. According to Smith, the separation of these two metals can be effected in solutions of the double salts with potassium cyanide. 1 In order to carry... out such an electrolysis from '50 to I'O grm. Copper sulphate, and at the most '50 grm. Mercuric chloride, are dissolved in water, and to this solution from 2-0 to 4'0 grms. Pure potassium cyanide are added. The clear solution after dilution to the usual volume is electrolysed with a current density of from -06 to '08 ampere.
At the normal temperature about sixteen hours will be found necessary to effect the separation of the mercury ; if the electrolyte be heated to 60 C. , the deposition of this metal can be effected in from three to four hours.
What to read after The Theory And Practice of Electrolytic Methods of Analysis?
You can find similar books in the "Read Also" column, or choose other free books by Bernhard Neumann to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
It follows therefore that this method stands far behind the two methods first described as regards simplicity and ac- curacy.
The electrolytic method of separating copper and silver could receive a practical application in the analysis of silver coining- metal, and this use of it will receive further notice in Part III. , D.
Copper from Quicksilver. According to Smith, the separation of these two metals can be effected in solutions of the double salts with potassium cyanide. 1 In order to carry... out such an electrolysis from '50 to I'O grm. Copper sulphate, and at the most '50 grm. Mercuric chloride, are dissolved in water, and to this solution from 2-0 to 4'0 grms. Pure potassium cyanide are added. The clear solution after dilution to the usual volume is electrolysed with a current density of from -06 to '08 ampere.
At the normal temperature about sixteen hours will be found necessary to effect the separation of the mercury ; if the electrolyte be heated to 60 C. , the deposition of this metal can be effected in from three to four hours.
What to read after The Theory And Practice of Electrolytic Methods of Analysis?
You can find similar books in the "Read Also" column, or choose other free books by Bernhard Neumann to read onlineMoreLess
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