The Treasures of Coal Tar

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If the fabric to be dyed is first im- pregnated ,with an alkaline solution of beta-naphthol and then immersed in a solution of diazotised para-nitraniline (no,<(^ yNH,), the dye, para- nitraniline red or para-red, is produced on the fibre. Dyeing with this pigment dye — ^as a dye produced on the fibre is called — ^is carried out on a very large scale, nearly two thousand tons of para-nitraniline being produced annually for the purpose. This process of dyeing can, similarly, be carried out with dyes containing an amino-group which can be diazotised on the fibre. Thus there is a very com- plex dye primuline, discovered by Professor A. G. Green in 1887, which will dye cotton directly of a yellow shade. This dye is somewhat fugitive, and is, consequently, of comparatively little value in itself. If, however, a piece of calico, dyed with primuline, is passed through a cold, dilute solution of nitrous acid, the primuline (which contains an amino-group), is diazotised; and if the fabric is then passed through a solution of an amine or phenol, a dye is produced or " developed " on the fibre.

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