Thermo Electromotive Force in Electric Cells the Thermo Electromotive Force Bet

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Thermo Electromotive Force in Electric Cells the Thermo Electromotive Force Bet
Henry S Henry Smith Carhart
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OO 19. 6 7567 7569 + . 03 25-3 7733 7744 + . 14 32-1 7943 7954 + . 14 37-3 8106 8114 + . 10 41. 8 8256 8253 - . 04 47-9 8460 8441 . 22 49-3 8486 8485 - . 01 In the diagram Fig. 23 the circles denote the observations for ZNS0 4 and the crosses those for ZnCl 2 . IN ELECTRIC CELLS 95 Bouty found the emf for zinc amalgam in all salts of zinc the same. 1 He calls attention to the fact that two copper electrodes plunged into sulphate of copper on one side and acetate of copper on the other gave an e...mf of about 0. 037 vo ^ with the copper in the acetate as the positive electrode. Further, M. V. . 6 10 20 30 40 50 Fig. 23 this emf was not modified by elevation of the temperature of the couple since the thermo- emfs at the two metal-liquid junctions were equal and opposed. The equality of the thermo-emfs between zinc amalgam and the sulphate and the chloride of zinc suggested that a cell made up of zinc amal- gam in zinc sulphate on one side and zinc chloride on the other would show a zero temperature 1 Jour, de Phys.

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