An Introduction to the Theory And Practice of Qualitative Analysis By Solution

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An Introduction to the Theory And Practice of Qualitative Analysis By Solution
Fernando Wood Martin
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A yellow- ish-red color in the CS 2 (Br) shows hydrobromic acid.
b. SI is present: If HI was found in 10, it must be removed be- fore testing for HBr. This is done by filtering out the iodine-saturated CS 2 by passing the fluid through a wet filter. The CS 2 remains on the filter. Treat the filtrate again with HNO 3, K 2 OO 4, and CS 2, filter, and repeat till no further trace of iodine is seen. Now treat the clear filtrate with chlorine gas and CS 2, as directed in a.
12. H(CN). Acidify 2-3 cc
.... Of Y with H 2 SO 4, * and imme- diately expose to the evolved gas a drop of (NH 4 ) 2 S in the loop of a platinum wire supported in a cork which rests loosely on the mouth of the test tube. After 10 minutes shake the drop onto a porcelain cruci- ble lid, evaporate it to dry ness at very gentle heat, and touch the res- idue with a drop of FeCl 3 . A deep-red coloration shows hydrocyanic acid.
2Na +, 2CN-+2H+, SO 4 ~=2Na +, SO"+ [2HCN]; (NH 4 ) 2 Sx-fH +, CN-=NH 4 SCN+H 2 S; 3NH 4 -SCN-{-Fe +++, Cl 3 -=3(NH 4 +, Cr)-h [Fe(CNS)J.


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