Distillation Principles And Processes

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For the very long still-heads, which could not conveniently be weighed, the estimated loss by evaporation +0-85 gram was sub- tracted from the difference between the original weight of the mixture and the sum of the weights of the fractions. The actual loss by evaporation, when measured, varied from 0-00 to 0-65 gram, and was greater for the large than the small still-heads.
The Plain Vertical Still-head, Although the plain vertical still- head is less efficient than any other, yet a certain am
...ount of fractiona- tion does take place in it, and it may be well to consider the effect of altering (a) its length, (b) its internal diameter. The influence of such alterations is shown in Table 49.
TABLE 49 PLAIN VERTICAL STILL- HE ADS Vertical height in cm.
12 62 120 From 62 to 70 cm.
Internal diameter in mm.
From 14 to 15-5 mm.
5-1 8-0 V 14-0 19-4 25-7 Final temperature.
Percentage weight of distillate.
83-2 86-2 0-1 1-0 0-5 0-4 0-1 1-3 0-2 89-2 2-1 12-8 19-4 22-2 16-2 12-8 15-2 20-0 92-3 28-4 21-5 16-6 16-5 18-3 21-5 19-4 18-8 95-4 18-0 11-0 10-6 9-2 11-7 11-0 11-2 9-2 98-5 10-9 8-9 7-2 7-2 8-7 8-9 8-6 7-2 101-6 8-6 7-4 6-5 5-8 7-5 7-4 6-1 4-7 104-6 7-2 6-2 6-0 5-5 5-8 6-2 5-6 5-9 107-6 7-2 7-3 6-1 5-9 6-9 7-3 6-6 6-4 110-0 6-8 8-4 7-S 7-1 8-2 8-4 9-5 10-0 110-6 6-9 9-0 8-1 8-9 9-5 9-0 8-0 7-2 Pure toluene by difference .


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