On the Calculation of Thermo Chemical Constants
On the Calculation of Thermo Chemical Constants
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, is used in the calculations ; and the molecular heats of combustion of the alcohols in this group have been calculated thereby, and are exhibited, together with the differ- ences between them and the experimental, and the percentage errors, in Table 19. The agreement is quite satisfactory, except in the case of trimethyl- carbinol.
This behaviour of the alcohols in thus dividing themselves into two groups with respect to the value of O) L is remarkable, inasmuch as it appears that the mere po...sition of the hydroxyl group exercises an influence upon its thermal equivalent, and is in marked contrast to the behaviour of the chlorine substituted hydrocarbons (see 8).
It may be, however, that the two hydrogen atoms in water are not bound to the oxygen atom with ORGANIC OXYGEN COMPOUNDS 45 equal affinity (see the case of ammonia, 26) in some alcohols one hydrogen atom being replaced, in others, the other hydrogen atom being replaced, depending pos- sibly upon the configuration of the rest of the mole- cule, whilst the thermal value of the C .
What to read after On the Calculation of Thermo Chemical Constants?
You can find similar books in the "Read Also" column, or choose other free books by Redgrove Herbert Stanley to read onlineMoreLess
To quickly assess the difficulty of the text, read a short excerpt:
, is used in the calculations ; and the molecular heats of combustion of the alcohols in this group have been calculated thereby, and are exhibited, together with the differ- ences between them and the experimental, and the percentage errors, in Table 19. The agreement is quite satisfactory, except in the case of trimethyl- carbinol.
This behaviour of the alcohols in thus dividing themselves into two groups with respect to the value of O) L is remarkable, inasmuch as it appears that the mere po...sition of the hydroxyl group exercises an influence upon its thermal equivalent, and is in marked contrast to the behaviour of the chlorine substituted hydrocarbons (see 8).
It may be, however, that the two hydrogen atoms in water are not bound to the oxygen atom with ORGANIC OXYGEN COMPOUNDS 45 equal affinity (see the case of ammonia, 26) in some alcohols one hydrogen atom being replaced, in others, the other hydrogen atom being replaced, depending pos- sibly upon the configuration of the rest of the mole- cule, whilst the thermal value of the C .
What to read after On the Calculation of Thermo Chemical Constants?
You can find similar books in the "Read Also" column, or choose other free books by Redgrove Herbert Stanley to read onlineMoreLess
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