Organic Chemistry volume 2

Cover Organic Chemistry volume 2
Organic Chemistry volume 2
W H William Henry Perkin
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1-095 at 20, and boils at 239. It has a peculiar charac- teristic smell, and is sparingly soluble in water, but it dissolves freely in dilute acids, forming crystalline salts, such as the hydrochloride, C 9 H 7 N, HC1, the sulphate, (C 9 H 7 N) 2, H 2 S0 4, &c. It also forms double salts, of which the platinochloride, (C 9 H 7 N) 2, H 2 PtCl 6 + 2H 2 0, and the bichromate, (C 9 H 7 N) 2, H 2 2 7, may be mentioned ; the latter, prepared by adding potassium bichromate to a solution of quinoline h...ydrochloride, crystal- lises from water, in which it is only sparingly soluble, in glistening yellow needles, melting at 164-167.
Quinoline is a tertiary base (compare p. 484), and com- bines, with methyl iodide, to form the additive product, quinoline methiodide, C 9 H 7 N, CH 3 I.
Constitution. As the relation between pyridine, C 5 H 5 N, and quinoline, C 9 H 7 N, on the one hand, is much the same as that between benzene, C 6 H 6, and naphthalene, C 10 H 8, on the other, both as regards chemical behaviour and molecular composition (the difference being C 4 H 2 in both cases), it might be assumed that quinoline is derived from pyridine, just as naphthalene is derived from benzene ; consequently the constitution of quinoline might be expressed by one of the following formulas : CH CH CH CH ^^\CH CH N CH CH I.


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