Outlines of Electrochemistry

Cover Outlines of Electrochemistry
Outlines of Electrochemistry
Harry Clary Jones
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per second.
O.OOW »' ♦* 0.00S4 " »» Knowing tiie absolute velocity of one ion, and the relative velocities of all the more common ions, we can calculate at once the absolute velocities of all of these ions for unit potential gradient.
The above results for the velocity of hydrogen, the swiftest of all ions, cannot but impress us by their small magnitude.
Perhaps, however, we should not be sur- prised after all at these figures, when we consider the enormous resistance offered to the movements o
...f the ions by the pres- ence of the solvent, which always has con- siderable viscosity. The comparatively free movements of the gaseous molecules through space cannot be compared with the movements of the ions through the resistent solvents, and yet we are tempted to try such comparisons, since the laws of gas-pressure apply to the osmotic pressure of solutions. It seems pretty clear that the cause of gas-pressure is to be found in the impacts of the rapidly moving gas- eous particles against the walls of the confining vessel.

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