Preparation And Reactions of Partially Fluorinated Dienes

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Ethanol addition gave only the 1,4 addition product in 67% yield.
The 1,4-perfluoropentadiene was found to be unreactive compared to (I) and (II). No 2 + 2 cycloaddition products were formed and no products from radical reactions were isolated except for the 1,2 addition product with bromine. None of the tetrabromo addition product or cyclized product was formed. Trif luoronitrosome thane gave no adducts at -78°C and at ambient temperature.
46 Tables VIII, IX and X give the reactions, products,
... and yields for each system, 1,1,2-trif luoropentadiene-1,3; 1,1,2,5,5,5- hexafluoropentadiene-1,3; and 1,4-perf luoropentadiene.
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