Quantitative Chemical Analysis

Cover Quantitative Chemical Analysis
Quantitative Chemical Analysis
C Remigius Fresenius
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SILICIC ACID. * When silicic acid is separated by acids from aqueous solutions of alkali silicates, it is at first perfectly soluble in water. It be- comes insoluble or rather difficultly soluble when it coagulates. Coagulation is a permanent change and is furthered by concentra- tion arid by elevation of temperature. Silicic acid solution con- taining 10 or 12 per cent, of SiO 2 coagulates at the ordinary tem- perature in a few hours, and immediately if heated. A solution of * Frje silicic aci...d in solution is assumed to have the composition expressed by the formula Si(OH) 4 . Silicic anhydride (SiO 2 ) is usually called "silica. " Compounds of SiO 2 with less water than corresponds to the formula Si(OH)4 =5 ^iO 2 (H 2 O)2 are here called " hydrates of silica, " 2o4 FORMS. [ 93.
5 per cent, may be preserved without coagulating for five or six days, one of 2 per cent, for two or three months, and one of 1 per cent, for several years, and solutions containing -fa per cent, or less are not appreciably altered by time.


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