Textbook of Physical Chemistry

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Determinations of the electri- cal conductances of solutions of many solvents, both organic and inorganic, have been made. These show that, as in the case of water, the conductance of the pure solvent is very small, while the solutions have a very appreciable conduct- ance. In most cases the conductance is less than in aqueous solutions, but in a few cases they conduct much better. Such inorganic solvents as NH 3, SO 2, and HCN yield solu- tions that conduct very well, in many cases as well as ...water solutions, while the solutions of various solutes in PC1 3, AsCl 3, etc. , have a relatively small conductance. A consideration of NONAQUEOUS SOLUTIONS 397 the various groups of organic solvents shows, in a general way, that liquid hydrocarbon solutions, as well as their halogen substitution products, are nonconductors. The alcohols yield solutions that conduct very well, but the conductance decreases with the increase of the carbon content as well as with the complexity of the alcohol. The aldehydes yield conducting solutions, and many of the solutions of ketones are excellent conductors, while the esters yield conducting solutions which are however not very good conductors.

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