The Chemical Synthesis of Vital Products And the Interrelations Between Organic
The Chemical Synthesis of Vital Products And the Interrelations Between Organic
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] Ettxanthone [136] gives quinol among the products of fusion with potash (Baeyer, Zeit. [2j 5, 569).
[N. ] Succinic acid [Vol. II] gives quinol among other products by the dry distillation of its salts (v. Richter, Journ. Pr. Ch. [2] 20, 207).
Or succinic acid (ester) by the action of sodium in presence of alcohol or of dry sodium ethoxide can be converted into succinylsuccinic (cyclohexanedione- 2 : 5-dicarboxylic- 1 : 4) ester (Fehling, Ann. 49, 186 ; Herrmann, Ber. 10, 107 ; Ann. 211, 306 ;... Duisberg, Ber. 16, 133 ; Volhard, Ibid. J 34 ; Piutti, Gazz. 20, 167; Vorlander, Ann. 28O, 186). The latter on oxidation by air or bromine gives p-dihydroxyterephthalic (quinol- dicarboxylic or 2 : 5-phenedioldicarboxy- lic) ester (Herrmann, loc. Cit. 1 1 1 ; Ann. 211, 327), and the acid on dry distilla- tion or on fusion with potash yields quinol (Ibid. Ber. 10, 1 1 2 ; Ann. 211, 33 6 )- Or succinylsuccinic ester can be con- verted into dihydroxyterephthalic acid by the action of phosphorus pentachloride (Levy and Curchod, Ber.
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To quickly assess the difficulty of the text, read a short excerpt:
] Ettxanthone [136] gives quinol among the products of fusion with potash (Baeyer, Zeit. [2j 5, 569).
[N. ] Succinic acid [Vol. II] gives quinol among other products by the dry distillation of its salts (v. Richter, Journ. Pr. Ch. [2] 20, 207).
Or succinic acid (ester) by the action of sodium in presence of alcohol or of dry sodium ethoxide can be converted into succinylsuccinic (cyclohexanedione- 2 : 5-dicarboxylic- 1 : 4) ester (Fehling, Ann. 49, 186 ; Herrmann, Ber. 10, 107 ; Ann. 211, 306 ;... Duisberg, Ber. 16, 133 ; Volhard, Ibid. J 34 ; Piutti, Gazz. 20, 167; Vorlander, Ann. 28O, 186). The latter on oxidation by air or bromine gives p-dihydroxyterephthalic (quinol- dicarboxylic or 2 : 5-phenedioldicarboxy- lic) ester (Herrmann, loc. Cit. 1 1 1 ; Ann. 211, 327), and the acid on dry distilla- tion or on fusion with potash yields quinol (Ibid. Ber. 10, 1 1 2 ; Ann. 211, 33 6 )- Or succinylsuccinic ester can be con- verted into dihydroxyterephthalic acid by the action of phosphorus pentachloride (Levy and Curchod, Ber.
What to read after The Chemical Synthesis of Vital Products And the Interrelations Between Organic?
You can find similar books in the "Read Also" column, or choose other free books by Raphael Meldola to read onlineMoreLess
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