The Chemistry of the Diazo Compounds
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NO (R denoting the metal)^ (2) Free phenylnitrosoamine, C 6 H 5 . NH. NO, does not exist, as a solution of its non-combining sodium salt, when acidified with acetic acid, immediately gives an azo-dyestuff with /J-naphthol.
(3) ^9-Nitrodiazobenzene appears to exist only in the nitrosoamine form, and its alkali salt does not exist in the ' oxime ' condition.
These conclusions, as will be shown, do not truly represent the course of the reactions (see p. 98).
In a paper published shortly after the ...appearance of Schraube and Schmidt's work, Bamberger stated that he had earlier discovered a derivative of /3-naphthylamme cor- H 98 CHEMISTRY OF THE DIAZO-COMPOUNDS responding to the formula C 10 H 7 . NH. NO, which did not couple with /3-naphthol, but did so after treatment with a mineral acid. * He considered that the influence of the latter was to effect a transformation into the isomeric diazo-compound, thus C 10 H 7 . NH. NO -> C 10 H 7 . N:N. OH.
Confirmation of this view was afforded by von Pechmann and Frobenius, who stated uhat the silver salt of ^-nitro- phenylnitrosoamine, when treated with methyl iodide, yielded an oxygen-ether of ^9-nitrodiazobenzene N0 2 .
What to read after The Chemistry of the Diazo Compounds?
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To quickly assess the difficulty of the text, read a short excerpt:
NO (R denoting the metal)^ (2) Free phenylnitrosoamine, C 6 H 5 . NH. NO, does not exist, as a solution of its non-combining sodium salt, when acidified with acetic acid, immediately gives an azo-dyestuff with /J-naphthol.
(3) ^9-Nitrodiazobenzene appears to exist only in the nitrosoamine form, and its alkali salt does not exist in the ' oxime ' condition.
These conclusions, as will be shown, do not truly represent the course of the reactions (see p. 98).
In a paper published shortly after the ...appearance of Schraube and Schmidt's work, Bamberger stated that he had earlier discovered a derivative of /3-naphthylamme cor- H 98 CHEMISTRY OF THE DIAZO-COMPOUNDS responding to the formula C 10 H 7 . NH. NO, which did not couple with /3-naphthol, but did so after treatment with a mineral acid. * He considered that the influence of the latter was to effect a transformation into the isomeric diazo-compound, thus C 10 H 7 . NH. NO -> C 10 H 7 . N:N. OH.
Confirmation of this view was afforded by von Pechmann and Frobenius, who stated uhat the silver salt of ^-nitro- phenylnitrosoamine, when treated with methyl iodide, yielded an oxygen-ether of ^9-nitrodiazobenzene N0 2 .
What to read after The Chemistry of the Diazo Compounds?
You can find similar books in the "Read Also" column, or choose other free books by John Cannell Cain to read onlineMoreLess
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