The Chemistry of the Secondary Batteries of Planté And Faure

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In Part II., when treating of the charging of the cell, we pointed out that in the electrolysis of dilute sulphuric acid between lead electrodes, two totally different reactions might be obtained.
The positive metal becomes thinly coated with lead sulphate when the current employed is ol small density, but with lead peroxide when the density of the current is of greater magnitude.
This latter action is, of course, what takes place in the ordinary formation of a Plants battery.
The chemical chan
...ge, therefore, which goes on at the positive electrode is to a certain extent dependent upon the strength of the current. It appeared also of both theoretical and practical interest to determine whether the chemical change was also influenced by the strength of the acid Digitized by Google BATTERIES OF PLANTA AND FAURE. 45 employed. Our experiments consisted in passing a current of uniform strength, about i ampere, between electrodes of lead, 12 square inches in size, in varying strengths of sulphuric acid, and estimating in each case the amount of oxygen fixed by the positive electrode.

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