The Owens College Junior Course of Practical Chemistry

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5. Heated with strong H 2 SO 4, the mixture darkens wo PRACTICAL CHEMISTRY.
rapidly from separation of carbon, and SO 2, CO, and CO 2 are evolved.
6. Heated to redness, the substance darkens in colour and gives off the characteristic odour of burnt sugar.
123. CITRIC ACID. C 6 H 8 O 7 .
i. CaCl 2 produces no precipitate in neutral solutions in the cold, but on boiling, Ca 3 (C 6 H 6 O 7 ) 2 is precipitated, and is not soluble in KHO, but soluble in (NH 4 )HO. * 2. Lime-water produces no precipi
...tate in cold neutral solutions, but on boiling, Ca 3 (C 6 H 5 O 7 ) 2 is precipitated.
3. AgNO 3 produces in neutral solutions a white floc- culent precipitate of C 6 H 5 Ag 3 O 7, soluble in (NH 4 )HO : this solution does not blacken on boiling.
4. Heated with strong H 2 SO 4, CO 2 and CO are evolved without any darkening in colour ; on continued heating, however, the mixture darkens, and SO 2 is evolved.
5. Heated to redness, irritating fumes are given off, readily distinguished from those given off by heating the preceding acid.


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