The Sulfonation of Benzene

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13 1. 52 0. 771 150 1 12. 74 3. 92 0. 765 0. 7647 2 6. 92 2. 14 0. 764 3 4. 60 1. 40 0. 765 160 2 9. 50 3. 00 0. 760 0. 7590 3 6. 26 2. 01 0. 758 170 1 8. 57 2. 91 0. 746 0. 746 DISCUSSION OF RESULTS The concentration of sulfuric acid decreases rapidly at first, and then more slowly as the sulfonation proceeds. A value is eventually reached below which the concentration does not seem to fall. This is probably due to the regenera- tion of sulfuric acid, which is formed by the decomposition of th...e monosulfonic acid into sulfuric acid and diphenylsulfone. This is particularly noticeable at 170 C. , where the sulfuric acid concentration becomes constant in the neighborhood of 0. 60 per cent.
The concentration of the monosulfonic acid increases rap- idly at first, then more slowly as the reaction proceeds, the rate being greater at the higher temperatures. The concen- tration reaches a maximum and then decreases, owing to the formation of diphenylsulfone. The maximum concentra- 10 OOf 11 , 2- \ 5.


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