Theoretical Chemistry From the Standpoint of Avogadros Rule Thermodynamics

Cover Theoretical Chemistry From the Standpoint of Avogadros Rule Thermodynamics
Theoretical Chemistry From the Standpoint of Avogadros Rule Thermodynamics
Nernst, Walther, 1864-1941
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1067 (1888).
214 THEORETICAL CHEMISTRY BOOK II occupy only -- =0 '000 16 of the apparent volume. We must therefore conclude that, even under the greatest pressures possible, hydrogen could not be compressed so as to occupy less space than jq-'ooth of what it occupies at and under 1 m. Pressure. 1 On the other hand, entirely in harmony with the supposition that the molecular attraction in the case of hydrogen is very small, is the observation made by Joule and Thomson (1854), that this gas, hydr
...ogen, was the only one of all those investigated that showed no cooling on expanding without the performance of external work.
Finally, it must be emphasised that the van der Waals' formula may claim to hold good only when the gas experiences no change in its molecular condition as its volume changes ; for the theory advanced above provides that the molecules, even under the highest degrees of con- densation, must remain single individuals, and not unite to form larger groups. It cannot be stated a priori whether or not this occurs in particular cases, but the accuracy of the formula makes this very probable.


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