Valentin's Practical Chemistry

Cover Valentin's Practical Chemistry
Valentin's Practical Chemistry
William George Valentin
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Na^S.Oa + ^ClNaO + OH, = 2HNaS0, + 4NaCl.
Na^SgOg gives with Fe^jCl^ at first a reddish violet coloration (difference between sulphites and thiosulphates), but on standing the solution is slowly decolorised (more readily on heating), with formation of FeCl^, thus : Na,S,03 4- 4Fe,Cls + 50H, = 2NaHS0, + 8FeCl, + 8HC1.
Nascent hydrogen reduces thiosulphates, and sulphuretted hydrogen is evolved : Na,S,03 + 4H, + 2HC1 = 2SH, + 30H, + 2NaCl.
Some sulphur is always precipitated as well.
Sodium thios
...ulphate is a useful solvent for haloid silver salts (for which it is much used in photogi-aphy), Hg^Cl, and PbSO^. Calcium t-hiosulphate, CaS^Og, is used as an agent for removing the last traces of chlorine in the bleaching of paper pulp, and from fabrics bleached ^y means of bleaching powder, to prevent their deterioration by the traces of chlorine which they are apt to retain. It has on that account received the name of "antichlor." The free hydrochloric acid which is formed in the reaction is neutralised by passing the fabrics through a weak alkali bath.

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